Ce-Uio-66，CAS#: 1801427-51-9

建筑材料公司名称：UIO-66(Ce)

别的英文名称：Ce-UIO-66-BDC

CAS：1801427-51-9

计量单位分子结构式C48H24O32Ce6

的单位团伙量1953.38

配位金属件Ce

配体    对苯二甲酸（CAS：100-21-0）

外径     0.8nm, 1.1nm

孔容     0.5 cm3/g

比面BET比单单从表面1100 m2/g

软件形貌    淡紫色粉未  

粒度      50-200nm 不規則小粒

操作文章：

公开的打了个种有机化学-金属件框架的涂料Ce-UiO-66在化学降解氯代芳烃类男人持久性无机被污染的物(POPs)中的应用领域。MOF用料具备条件大比的表面积和多孔特征，需要做为平台担载五金混合物，增长自己了五金的发散度，然而有助于于增长自己促使剂的活力。主活力混合物为Ce,催化氧化剂的比表明积为1000-1200m2/g，微孔过滤设备构造。无机金属制框架图村料Ce-UiO-66能够温度离子液体生物降解氯代芳烃类POPs。

We synthesized a CuO/CeO2 catalyst using a copper ions encapsulated ceria metal-organic framework (MOF) Ce-UiO-66 as the precursor. The CuO/CeO2 catalysts derived by calcining the MOF precursor (the x-CuCe catalysts) showed the better activity and selectivity for the preferential CO oxidation in the H2-rich stream than the CuO/CeO2 catalyst prepared by wetness impregnation (CuCe-im). A temperature window to match the CO conversion and O2 to CO2 selectivity higher than 99.5% at the same time appeared using the x-CuCe catalysts as the catalyst. Raman and XPS results indicated that more oxygen vacancies were formed in the bulk of ceria in the x-CuCe catalysts than that in the CuCe-im catalyst, which could promote the mobility of oxygen. Our results indicated that the surface lattice oxygen and the oxygen vacancies in the bulk of ceria could enhance the catalytic performance of the CuO/CeO2 catalysts.

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