学术论文：mPEG-炔烃的二硫化碳气体吸附和熔融表现超链接：//www.sciencedirect.com/science/article/abs/pii/S0896844621000218原作者：S. 洛佩斯，乔丹· 拉莫斯，JM García-Vargas，加西亚 山，JF 罗德里格斯，伊 ·格拉西亚节选：抽象概念的介绍 mPEG-炔烃和超临介 CO 2 (scCO 2 ) 混物的相情形和研究分析缔合物沸点的变是制定相当基本操作标准和开放高压低压施工工艺的需要先决标准，这样可以有 mPEG-炔烃与药物治疗或蛋白酶质的共轭物。在任何运作中，了解到粘附 CO 2会造成 mPEG-炔烃的沸点体温渐渐减低。应用改进的克劳修斯-克拉多珀龙式子将有的热分解体温相关了起来。应用选择外部策略的可调体型大小了解室制定CO 2在 mPEG-炔烃中的均衡性粘附。他们调查是在 308 至 318 K 的体温範圍内并且 8–17 MPa 的负荷下开始的。分析评估了亨利基本定律、双模式英文、桑切斯-拉孔布壮态式子和道理式绘图的預測工作能力。

AbstractThe understanding of the phase behaviour of the mixture mPEG-alkyne and supercritical CO2 (scCO2) and the study of the variation of the polymer melting point are essential prerequisites in order to determine appropriate operating conditions and develop high pressure processes that allow the obtention of a conjugate mPEG-alkyne with a drug or a protein. In this work, it was observed a progressive decrease of the melting point temperature of mPEG-alkyne induced by the adsorption of CO2. The obtained melting temperatures were correlated using a modification of the Clausius Clapeyron equation. The equilibrium sorption of CO2 into mPEG-alkyne was determined with a variable-volume view cell employing a static method. These experiments were carried out in the temperature range 308 and 318 K, and at 8–17 MPa of pressure. The prediction capabilities of the models of Henry’s Law, Dual-Mode, Sanchez Lacombe Equation of State and Heuristic Model was evaluated.浙江杏彩体育平台 生态学展示相关联护肤品：DSPE-Cap-BiotinDMG-PEG2000C18-PEGn-OPSSDSPE-PEG-NTA-NIDPPE-PEG-NH2DSPE-PEG-COOH（二硬脂酰基磷脂酰乙酸乙酯胺-聚乙二醇-羧基)这些文章标题方式的来源各样期刊论文或文章，此事侵犯商标权请取得联系你们删除文件！