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四氨基钴酞菁（TaPcCo-MWCNTs）共价修饰MWCNTLi-S氧化还原催化剂
发布时间：2020-11-13     作者：wyf   分享到：

四氨基钴酞菁（TaPcCo-MWCNTs）共价突显MWCNTLi-S钝化回归杂多酸的作用剂

关键点词：锂硫干电池，共价修饰语，四氨基酞菁钴，多壁碳微米管

开放好几个种**的Li-S阳极氧化保存催化反应氧化剂，该催化反应氧化剂由被四氨基钴酞菁（TaPcCo-MWCNTs）共价装饰的MWCNT构成。**的多加硫锂（LiPS）猎取是依据含N的硫亲硫酞菁环和耐Co中央硫电子层构建的。一些活性炭吸附如何设计进行了Co未被抢占的d路轨用于微电子超置换速度铁路桥。无机化学物质精确测量和高密度泛函方法论计算方法探求了LiPSs在色谱仪中的推流体力学化学反应各类液固转移。Li 2的均沉积物还检查快到S膜，该膜在电瓶无限循环过程中 中留存了负极全部性和硫的用率。很快的电子元器件和锂铁离子借助导电的MWCNT骨架和TaPcCo上的亲硫转变成基氨基高速 来回于的反应位点，也大幅度驱动了促使的硫腐蚀重现。采用在金属电极金属涂层中增长6 wt％的TaPcCo-MWCNT，也可以达成达7 mg cm -2的体积硫电流量，得以保持高硫采用率。在1 C放到5 mg cm -2的硫装载下实现了了安稳的长时巡环，初始值大小储电量为4.4 mAh cm -2，调取的3.5 mAh cm -2500个过渡期后。考量到酞菁大原子核的高结构设计多元化性，本科学研究为最新科技Li-S催化反应剂作为了机会英语。

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锂硫锂充电有的是种新网络体系再次锂充电，由于高比正能量、区域友好合作等特殊性，促使了朋友**的关注度。其实锂硫锂充电的开发仍要面临巨大的技术水平击败。含硫活性酶类类物质的导电性较强，充发出电整个的过程中的反馈频率速度慢，正极的硫的充分利用匮乏。除此以外，正极在充发出电整个的过程中会产生可溶解性的多塑炼锂，其在 -极彼此的“穿越效果”产生锂电池库伦使用率和循环法稳定的性的较低。

按照化学上上掩盖的办法将导电的碳纳米技术管与轻金属酞菁类结合实际物以化学上上键合的形式结合实际，拥有的锂硫正极催化剂的作用文件**提高自己了锂硫电池充电在高机构大小载硫量条件下的比容积、倍数性能指标和再循环相对稳界定。

金属制酞菁是存在18π光学框架的重金属-N4大环共轭网络体系，享有**的催化剂的作用能。学校金属件氧分子不齐全使用率的dz轨道交通为导电碳材料和多塑炼物内的光电对换展示 了过道，酞菁搭配物以至于外边代替基涉及到多的化学性质基团，在催化剂的用途多塑炼物转为的同时可产生良好的降解用途。该实验组织将四氨基酞菁钴与多壁碳纳米技术管用肿胺（C-NH-C）共价接连，构成了4-6nm的外层淡化层。该结构设计长期保持了多壁碳纳米技术管的高导电性，表层不光滑分布区的四氨基酞菁钴作为了丰富的的亲硫可溶性位点（Co）和亲锂可溶性位点（N）。在Co-N4和周边转变基氨基（-NH2）的信息化效应下，建筑材料是可以**地离心分离多混炼物并**挺高其高效液相和液-固导出进程的不良反应速度，**多加硫锂的“游来相应”，加速蓄电池放电代谢物Li2S的竖直形核与成长。就算在高组织表面积载硫量（7mg·cm-2）并且相对较大系数下（4C），正极也要实现较高的出水量和反复的动态平衡性，電池的安全性能到了**的提高了。

杏彩体育平台 提供食品：

产品名称别名英文名称cas
酞菁二锂
Phthalocyanine Dilithium25510-41-2
5,10,15,20-四苯基-21H,23H-卟啉锌(II)
锌(II)TPP		四苯基卟啉锌(II)5,10,15,20-Tetraphenyl-21H,23H-porphine Zinc(II)
Zinc(II) TPP		14074-80-7
2,3,7,8,12,13,17,18-八乙基卟啉2,3,7,8,12,13,17,18-八乙基-21H,23H-卟吩2,3,7,8,12,13,17,18-Octaethylporphyrin2683-82-1
二氯酞菁锡(IV)酞菁二氯化锡(IV)Tin(IV) Phthalocyanine Dichloride18253-54-8
酞菁二钠
Disodium Phthalocyanine25476-27-1
5,10,15,20-四(2,4,6-三甲苯基)卟啉5,10,15,20-四(2,4,6-三甲苯基) -21H,23H-卟吩5,10,15,20-Tetrakis(2,4,6-trimethylphenyl)porphyrin56396-12-4
5,9,14,18,23,27,32,36-八丁氧基-2,3-萘酞菁铜(II)
铜(II)-5,9,14,18,23,27,32,36-八丁氧基-2,3-萘酞菁		5,9,14,18,23,27,32,36-Octabutoxy-2,3-naphthalocyanine Copper(II)Copper(II) 5,9,14,18,23,27,32,36-Octabutoxy-2,3-naphthalocyanine155773-67-4
四苯基卟啉氯化铁(III)5,10,15,20-四苯基-21H,23H-卟啉氯化铁(III)
5,10,15,20-Tetraphenyl-21H,23H-porphine Iron(III) Chloride		Iron(III) Tetraphenylporphyrin Chloride16456-81-8
酞菁铁(II) (升华提纯)Phthalocyanine Iron(II) (purified by sublimation)Iron(II) Phthalocyanine (purified by sublimation)132-16-1
[5-[双(4-己基苯基)氨基]-15-[2-(4-羧基苯基)乙炔基]-10,20-双(3,5-二-叔丁基苯基)卟啉]合锌(II)YD2[5-[Bis(4-hexylphenyl)amino]-15-[2-(4-carboxyphenyl)ethynyl]-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)1201915-91-4
酞菁锡(II)Phthalocyanine Tin(II)Tin(II) Phthalocyanine15304-57-1
酞菁镁(II)Phthalocyanine Magnesium(II)Magnesium(II) Phthalocyanine1661-03-6
5,10,15,20-四(2,6-二氯苯基)卟吩5,10,15,20-四(2,6-二氯苯基)卟啉5,10,15,20-Tetrakis(2,6-dichlorophenyl)porphyrin37083-37-7
2,3,7,8,12,13,17,18-八氟-5 ,10,15,20-四(五氟苯基)卟啉全氟-5,10,15,20-四苯基-21H,23H-卟啉2,3,7,8,12,13,17,18-Octafluoro-5,10,15,20-tetrakis(pentafluorophenyl)porphyrin121399-88-0
酞氰化锌 (升华提纯)酞菁锌Zinc Phthalocyanine (purified by sublimation)14320-04-8
5,15-二苯基卟啉5,15-二苯基-21H,23H-卟吩5,15-Diphenylporphyrin22112-89-6
酞菁铅(II)Phthalocyanine Lead(II)Lead(II) Phthalocyanine15187-16-3
酞菁钴(II) (升华提纯)
Cobalt(II) Phthalocyanine (purified by sublimation)3317-67-7
2,3,9,10,16,17,23,24-八氟酞菁铜(II) (升华纯化)2,3,9,10,16,17,23,24-Octafluorophthalocyanine Copper(II) (purified by sublimation)
F8CuPc (purified by sublimation)		Copper(II) 2,3,9,10,16,17,23,24-Octafluorophthalocyanine (purified by sublimation)148651-60-9
2,9,16,23-四叔丁基酞菁铜(II)4,4',4',4'-四叔丁基酞菁铜Copper(II) 2,9,16,23-Tetra-tert-butylphthalocyanine39001-64-4
四苯基卟啉钴(II)5,10,15,20-四苯基-21H,23H-卟吩钴(II)
TPP钴(II)		Cobalt(II) Tetraphenylporphyrin14172-90-8
四苯基卟啉铜(II)5,10,15,20-四苯基-21H,23H-卟啉铜(II)
铜(II)TPP		Copper(II) Tetraphenylporphyrin14172-91-9
酞菁氯化铝铝酞菁Phthalocyanine Chloroaluminum14154-42-8
1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-十六氟酞菁铜(II) (升华提纯)F16CuPc (purified by sublimation)1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-Hexadecafluorophthalocyanine Copper(II) (purified by sublimation)14916-87-1
酞菁蓝酞菁铜(II),90%（β型）Phthalocyanine Blue147-14-8
颜料蓝16 (升华提纯)Pigment Blue 16 (purified by sublimation)Phthalocyanine (purified by sublimation)574-93-6
5,10,15,20-四(4-羧基甲氧苯基)-卟啉5,10,15,20-四(4-羧基甲氧苯基)-21H,23H-卟吩5,10,15,20-Tetrakis(4-carboxymethyloxyphenyl)porphyrin127812-08-2
5,10,15,20-四(对甲苯基)卟啉5,10,15,20-四(4-甲苯基)卟啉5,10,15,20-Tetrakis(p-tolyl)porphyrin14527-51-6
5,10,15,20-四(4-羟苯基)卟啉5,10,15,20-四(4-羟苯基)-21H,23H-卟吩5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin51094-17-8
5,10,15,20-四(3,5-二甲氧苯基)卟啉5,10,15,20-四(3,5-二甲氧苯基)-21H,23H-卟吩5,10,15,20-Tetrakis(3,5-dimethoxyphenyl)porphyrin74684-34-7
内消旋-四苯基卟吩
meso-Tetraphenylchlorin2669-65-0
meso-四(4-羧基苯基)卟吩四甲酯5,10,15,20-四(4-甲氧羰基苯基)卟啉5,10,15,20-Tetrakis(4-methoxycarbonylphenyl)porphyrin22112-83-0
5,10,15,20-四(4-氨基苯基)卟啉5,10,15,20-四(4-氨基苯基)-21H,23H-卟吩5,10,15,20-Tetrakis(4-aminophenyl)porphyrin22112-84-1
5-(4-羧苯基)-10,15,2-三苯基卟啉5-(4-羧苯基)-10,15,2-三苯基-21H,23H-卟吩5-(4-Carboxyphenyl)-10,15,20-triphenylporphyrin95051-10-8
5,10,15,20-四(五氟苯基)卟啉5,10,15,20-四(五氟苯基)-21H,23H-卟吩5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin25440-14-6
5,10,5,20-四(3,5-二羟苯基)卟啉5,10,5,20-四(3,5-二羟苯基) -21H,23H-卟吩5,10,15,20-Tetrakis(3,5-dihydroxyphenyl)porphyrin145764-54-1
酞菁绿G颜料绿 7Pigment Green 71328-53-6
5,15-双(苯乙炔基)-10,20-双[(三异丙基硅烷基)乙炔基]卟吩]]合镁(II)
[5,15-Bis(phenylethynyl)-10,20-bis[(triisopropylsilyl)ethynyl]porphyrinato]magnesium(II)1397288-30-0
锡(IV) 2,3-二氯化萘酞菁二氯(2,3-萘酞氰基)锡(IV)Tin(IV) 2,3-Naphthalocyanine Dichloride26857-61-4
5,10,15,20-四(4-甲氧苯基)-21H,23H-卟吩5,10,15,20-四(4-甲氧苯基)卟啉5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrin22112-78-3
氧钛酞菁 (升华提纯)酞菁氧钛/氧化(酞菁)钛Titanyl Phthalocyanine (purified by sublimation)26201-32-1
四苯基卟吩Tetraphenylporphine (Chlorin free)
TPP (Chlorin free)		Tetraphenylporphyrin (Chlorin free)917-23-7
5-(4-甲氧羰基苯基)-10,15,2-三苯基卟吩5-(4-Carbomethoxyphenyl)-10,15,20-triphenylporphyrin5-(4-Methoxycarbonylphenyl)-10,15,20-triphenylporphyrin119730-06-2
[5,10,15,20-四(4-甲氧苯基)卟啉]合钴(II)[5,10,15,20-四(4-甲氧苯基)-21H,23H-卟吩]合钴(II)
卟啉钴		[5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato]cobalt(II)28903-71-1
5,10,15,20-四(4-吡啶基)卟啉5,10,15,20-四(4-吡啶基)-21H,23H-卟啉5,10,15,20-Tetra(4-pyridyl)porphyrin16834-13-2
四(4-羧苯基)卟吩TCPP [=四(4-羧苯基)卟吩] [铜和镉用超高灵敏分光光度试剂][用于以HPLC进行的金属同时测定]Tetrakis(4-carboxyphenyl)porphyrin14609-54-2
5,10,15,20-四(4-磺苯基)卟啉
四苯基卟啉四磺酸		TPPS (=四苯基卟啉四磺酸水合物)5,10,15,20-Tetrakis(4-sulfophenyl)porphyrin
Tetraphenylporphyrin Tetrasulfonic Acid		35218-75-8
二氰基吡嗪类&类似物 [酞菁砌块]

2-氨基-4,5-二氰基-1H-咪唑2-氨基-4,5-咪唑二甲腈2-Amino-4,5-dicyano-1H-imidazole40953-34-2
1,4,5,6-四氢-5,6-二氧-2,3-二氰基吡嗪1,4,5,6-四氢-5,6-二氧-2,3-吡嗪二甲腈1,4,5,6-Tetrahydro-5,6-dioxo-2,3-pyrazinedicarbonitrile36023-64-0
5,6-二氨基-2,3-二氰基吡嗪2,3-二氰基-5,6-二氨基吡嗪5,6-Diamino-2,3-dicyanopyrazine36023-58-2
2,3-二氰基-5-甲基吡嗪5-Methyl-2,3-pyrazinedicarbonitrile2,3-Dicyano-5-methylpyrazine52197-12-3
吡啶-2,3-二甲腈2,3-二氰基吡啶Pyridine-2,3-dicarbonitrile17132-78-4
2,3-二氰基吡嗪吡嗪-2,3-二甲腈2,3-Dicyanopyrazine13481-25-9
4,5-二氰基咪唑DCI/4,5-二氰咪唑4,5-Dicyanoimidazole1122-28-7
5,6-二氯-2,3-二氰基吡嗪5,6-Dichloro-2,3-pyrazinedicarbonitrile5,6-Dichloro-2,3-dicyanopyrazine56413-95-7
2,3-二氰基-5-氨基-6-氯吡嗪5-氨基-6-氯-2,3-二氰基吡嗪5-Amino-6-chloro-2,3-dicyanopyrazine56413-96-8
邻苯二甲腈类 [酞菁砌块]

4-硝基邻苯二甲腈1,2-二氰基-4-硝基苯4-Nitrophthalonitrile31643-49-9
1,3-二亚氨基异吲哚啉
1,3-Diiminoisoindoline57500-34-2
4-碘酞腈1,2-二氰基-4-碘苯4-Iodophthalonitrile69518-17-8
3-硝基邻苯二甲腈1,2-二氰基-3-硝基苯3-Nitrophthalonitrile51762-67-5
4-(4-α-异丙苯基苯氧基)苯二甲腈2-[4-(3,4-Dicyanophenoxy)phenyl]-2-phenylpropane4-(4-α-Cumylphenoxy)phthalonitrile83482-57-9
4-戊氧基苯二甲腈4-戊氧基邻苯二甲腈4-Pentyloxyphthalonitrile106943-83-3
4-溴邻苯二甲腈4-溴-1,2-二氰基苯4-Bromophthalonitrile70484-01-4
4-正丁氧基-1,2-二氰苯4-丁氧基邻苯二甲腈4-Butoxyphthalonitrile81560-32-9
4-己氧基苯二甲腈1,2-Dicyano-4-hexyloxybenzene4-Hexyloxyphthalonitrile104949-82-8
4-丙氧基邻苯二甲腈4-丙氧基苯二甲腈4-Propoxyphthalonitrile106144-18-7
4-氨基邻苯二甲腈3,4-二氰基苯胺4-Aminophthalonitrile56765-79-8
1,2-二氰基-4-氟苯4-氟邻苯二腈4-Fluorophthalonitrile65610-14-2
4,5-二氟酞腈1,2-二氰基-4,5-二氟苯4,5-Difluorophthalonitrile134450-56-9
4,5-二氨基酞腈1,2-二氨基-4,5-二氰基苯4,5-Diaminophthalonitrile129365-93-1
4-(2',6'-二甲基苯氧基)邻苯二甲腈1,2-二氰基-4-(2',6'-二甲基苯氧基)苯4-(2',6'-Dimethylphenoxy)phthalonitrile221302-75-6
4,5-二氯邻苯二甲腈1,2-二氯-4,5-二氰基苯4,5-Dichlorophthalonitrile139152-08-2
邻苯二甲腈1,2-二氰基苯Phthalonitrile91-15-6
全氯邻苯二甲腈四氯邻苯二甲腈Tetrachlorophthalonitrile1953-99-7
4-叔丁基邻苯二甲腈4-叔丁基-1,2-二氰基苯4-tert-Butylphthalonitrile32703-80-3
四氟邻苯二甲腈3,4,5,6-四氟邻苯二甲腈Tetrafluorophthalonitrile1835-65-0
4-羟基邻苯二甲腈3,4-二氰基苯酚4-Hydroxyphthalonitrile30757-50-7
1,2-Dicyano-4-dodecyloxybenzene4-十二烷氧基邻苯二甲腈4-Dodecyloxyphthalonitrile161082-75-3
1,2,4,5-四氰基苯1,2,4,5-苯四甲腈1,2,4,5-Tetracyanobenzene712-74-3
2,3-二氰基对苯二酚3,6-二羟基邻苯二甲腈
2,3-二氰基羟基醌
3,6-二羟基邻苯二腈
3,6-二羟基邻苯二甲氰
2,3-二氰基氢醌		2,3-Dicyanohydroquinone4733-50-0
萘二甲腈类 [酞菁砌块]

1,2-萘二甲腈1,2-二氰基萘1,2-Naphthalenedicarbonitrile19291-76-0
1,3-二亚氨基苯并[f]异吲哚啉
1,3-Diiminobenz[f]isoindoline65558-69-2
2,3-二氰基-6-硝基萘
2,3-Dicyano-6-nitronaphthalene184026-06-0
2,3-二溴-6,7-二氰基萘6,7-Dibromonaphthalene-2,3-dicarbonitrile2,3-Dibromo-6,7-dicyanonaphthalene74815-81-9
2,3-二氰基-1,4-二羟基-5-硝基萘2,3-二氰基-5-硝基-1,4-萘二醇2,3-Dicyano-1,4-dihydroxy-5-nitronaphthalene4655-62-3
6-溴-2,3-二氰基萘6-溴萘-2,3-二甲腈6-Bromo-2,3-dicyanonaphthalene70484-02-5
2,3-二氰基萘2,3-萘二甲腈2,3-Dicyanonaphthalene22856-30-0
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